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排序方式: 共有3921条查询结果,搜索用时 15 毫秒
1.
当前锂离子动力电池电化学模型存在模型复杂、建模难度大、计算效率低、老化评估效果差的问题,本文提出一种考虑电池衰退老化的机理模型(ADME).本文首先通过有限差分法对伪二维(P2D)电化学模型进行离散降阶处理,得到简化伪二维(SP2D)模型.在SP2D模型的基础上,基于阴阳两极发生的副反应导致的衰退老化现象,提出一种考虑电池衰退老化的机理模型.其次,使用多变量偏差补偿最小二乘法实现模型参数辨识.最后通过动力电池衰退老化性能循环实验,对比分析了恒流、脉冲工况下SP2D模型和ADME模型的终端电压输出.结果表明:ADME模型较为简单、计算效率和估算精度高,可以有效评估电池容量老化衰退,得到理想的锂离子动力电池外特性曲线. 相似文献
2.
Jie Wang Cuicui Ma Qiannan Li Xing Wang Yang Yang Lingjian Yang Wei Jiang Sha Liao Shixiang Wang Pu Jia Ye Zhao Xiaohui Zheng 《Biomedical chromatography : BMC》2019,33(3)
Tanshinol borneol ester (DBZ) is a potential drug candidate composed of danshensu and borneol. It shows anti‐ischemic and anti‐atherosclerosis activity. However, little is known about its metabolism in vivo. This research aimed to elucidate the metabolic profile of DBZ through analyzing its metabolites using high‐performance liquid chromatography combined with electrospray ionization quadrupole time‐of‐flight mass spectrometry. Chromatographic separation was performed on an Agilent TC‐C18 column (150 × 4.6 mm, 5.0 μm) with gradient elution using methanol and water containing 0.2% (v/v) formic acid as the mobile phase. Metabolite identification involved analyzing the retention behaviors, changes in molecular weights and MS/MS fragment patterns of DBZ and its metabolites. As a result, 20 potential metabolites were detected and tentatively identified in rat plasma, urine and feces after administration of DBZ. DBZ could be metabolized to O‐methylated DBZ, DBZ‐O‐glucuronide, O‐methylated DBZ‐O‐glucuronide, hydroxylated DBZ and danshensu. Danshensu, a hydrolysis product of DBZ, could further be transformed into 12 metabolites. The proposed method was confirmed to be a reliable and sensitive alternative for characterizing metabolic pathways of DBZ and providing valuable information on its druggability. 相似文献
3.
AbstractWe study the inverse problem of parameter identification in noncoercive variational problems that commonly appear in applied models. We examine the differentiability of the set-valued parameter-to-solution map using the first-order and the second-order contingent derivatives. We explore the inverse problem using the output least-squares and the modified output least-squares objectives. By regularizing the noncoercive variational problem, we obtain a single-valued regularized parameter-to-solution map and investigate its smoothness and boundedness. We also consider optimization problems using the output least-squares and the modified output least-squares objectives for the regularized variational problem. We give a complete convergence analysis showing that for the output least-squares and the modified output least-squares, the regularized minimization problems approximate the original optimization problems suitably. We also provide the first-order and the second-order adjoint method for the computation of the first-order and the second-order derivatives of the output least-squares objective. We provide discrete formulas for the gradient and the Hessian calculation and present numerical results. 相似文献
4.
结构柔度矩阵需由质量矩阵归一化振型获得,而质量矩阵归一化振型难以直接测得,限制了柔度曲率类损伤指标的应用。为分析振型归一化方法对梁结构柔度曲率类损伤指标的影响,根据梁结构的刚度、弯矩和位移曲率的关系,建立了均布荷载作用下结构损伤前后位移曲率与损伤程度的理论表达式,实现定量分析均匀荷载面曲率结构损伤程度。提出P-范数振型归一化方法,通过均匀荷载面曲率指标推导了振型质量矩阵归一化系数差x_α与损伤程度的关系。以三跨连续梁算例对理论进行了验证,结果表明,损伤程度定量指标效果良好,不同P-范数振型归一化方法下,损伤程度的偏差可由2x_α估算;2-范数振型归一化方法的损伤识别结果与质量矩阵振型归一化结果最接近,故当无法获得质量矩阵归一化振型时,可采用2-范数归一化振型代替。 相似文献
5.
This work deals with a study of the dynamic and buckling analysis of polymer hybrid composite(PHC) beam. The beam has variable thickness and is reinforced by carbon nanotubes(CNTs) and nanoclay(NC) simultaneously. The governing equations are derived based on the first shear deformation theory(FSDT). A three-phase HalpinTsai approach is used to predict the mechanical properties of the PHC. We focus our attention on the effect of the simultaneous addition of NC and CNT on the vibration and buckling analysis of the PHC beam with variable thickness. Also a comparison study is done on the sensation of three impressive parameters including CNT, NC weight fractions, and the shape factor of fillers on the mechanical properties of PHC beams,as well as fundamental frequencies of free vibrations and critical buckling load. The results show that the increase of shape factor value, NC, and CNT weight fractions leads to considerable reinforcement in mechanical properties as well as increase of the dimensionless fundamental frequency and buckling load. The variation of CNT weight fraction on elastic modulus is more sensitive rather than shear modulus but the effect of NC weight fraction on elastic and shear moduli is fairly the same. The shape factor values more than the medium level do not affect the mechanical properties. 相似文献
6.
应用Hamilton原理建立了双路传力的无轴承旋翼运动方程。采用均匀入流模型,基于直升机飞行平衡条件,建立了无轴承旋翼柔性梁载荷的计算模型,并通过算例验证了模型的精度。利用该模型,研究了全机重心位置、机身气动阻力以及平尾安装角对柔性梁载荷特性的影响,给出了各因素对柔性梁载荷的影响趋势,得出了降低柔性梁载荷的方法。数值结果表明:2cm左右重心位置的变化能够引起9%~11%的柔性梁载荷变化量,15%气动阻力的增加会导致约9%的柔性梁载荷的增大;2°平尾安装角的变化引起约10%柔性梁载荷的变化量,3°平尾安装角的变化引起约26%柔性梁载荷的变化。 相似文献
7.
Understanding the complicated failure mechanisms of hierarchical composites such as fiber yarns is essential for advanced materials design. In this study, we developed a new Monte Carlo model for predicting the mechanical properties of fiber yarns that includes statistical variation in fiber strength. Furthermore, a statistical shear load transfer law based on the shear lag analysis was derived and implemented to simulate the interactions between adjacent fibers and provide a more accurate tensile stress distribution along the overlap distance. Simulations on two types of yarns, made from different raw materials and based on distinct processing approaches, predict yarn strength values that compare favorably with experimental measurements. Furthermore, the model identified very distinct dominant failure mechanisms for the two materials, providing important insights into design features that can improve yarn strength. 相似文献
8.
In structural dynamics, similitude laws usually deal with simple configurations as thin flat plates with point forces. Only recently, few papers have analyzed stiffened shells or stochastic pressure loads.This research activity extends the applicability of some similitude laws, developed for thin flat plates under a turbulent boundary layer load, to ribbed plates forced by the same wall pressure fluctuations.The work addresses the problem of designing a scaled experimental test-article and, successively, of re-modulating the measured data in order to get the structural response of an original (unscaled) configuration.Due to the complexity of the structural domain, the design of a scaled configuration leads to a distorted similitude. Then, a simple approach, to circumvent the distortion effects, is proposed. 相似文献
9.
提出一种改进的克隆选择算法用于解决混沌系统的参数辨识问题.该算法利用抗体的高频变异和受体编辑两种机制有效平衡算法的全局探索与局部开发,并引入向精英抗体学习策略进一步提高算法的收敛质量.对10个优化问题的实验表明:所提出算法在求解精度、收敛速度以及稳定性方面具有更好的性能.以参数未知统一混沌系统的同步控制为研究对象,合理设计同步控制器,并对同步系统的稳定性进行理论分析.通过对同步比例因子的设置,实现统一混沌系统的完全同步、反同步、投影同步等多种同步方式.仿真实验结果表明该方法能够实现对未知系统参数的精确辨识以及驱动-响应系统的有效同步控制,验证了所提方法的可行性与有效性. 相似文献
10.
在由多个并行零件生产线和装配线组成的产品生产物流中, 各生产线的瓶颈工序制约了装配节点及其整个生产物流的平衡. 为此, 基于约束理论和JIT(Just In Time)思想, 提出主、次瓶颈的概念及其判别方法和主瓶颈拉动次瓶颈、瓶颈前后拉动生产与平行顺序移动生产相结合的生产策略, 研究了基于负荷率的瓶颈工序负荷控制方法和主瓶颈触发次瓶颈拉式生产的时间控制方法, 使瓶颈工序利用率最大化, 各个零件到达装配节点的同步性得到改善. 算例的SIMIO仿真结果表明, 装配节点的在制品存量大幅度减少, 利用率提高. 相似文献